Ethyl ethanoate, acetic acid ethyl ester, acetic ester. If seeking medical attention, provide sds document to physician. The speed of hydrolysis of the vinyl acetate is 1,000 times greater than its saturated analogous in a alkaline medium, and it was researched that its speed of hydrolysis is significantly lower at a p. The vapor irritates the eyes starting with 20 ppm, while the detection threshold is reported to be about 0. Identification product name scintillation surfactant cat no. Liquid may cause sev ere irritation and transient corneal damage.
Vinyl acetate can polymerize uncontrollably hence it is shipped with polymerization. Vinyl acetate lm used in glass lamination intended use. The basis for the proposed limits is an epidemiologic report by deese and joyner 1969ex. Pdf preparation of divinyl esters by transvinylation. Sections i health hazard assessments for noncarcinogenic effects and. American polymer standards corporation safety data sheet page 2 of 5 polyvinyl acetate section 5. Vinyl acetate monomer vam is an essential chemical building block used in a wide variety of industrial and consumer products. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Vinyl acetate from ethylene, acetic acid and oxygen industrial plant simulation. Inhalation of vapors may result in dizziness or suffocation. Polyoxyethylene 10 octyl phenol recommended use laboratory chemicals. The extent and way in which vinyl acetate affects these systems is not well understood. Acute exposure to vinyl acetate monomer may require decontamination and life support for the victims. Dusts and vapours or fumes evolved during thermal processing may cause irritation to the respiratory system.
Iarc monographs on the evaluation of carcinogenic risks to humans. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Sampling and analytical methods vinyl acetate organic. Safety data sheet revision date 17jan2018 revision number 3 1. One reagent lane fair lawn, nj 07410 for information in north america, call. Toxicological profile for vinyl acetate agency for toxic. Paper open access related content polyvinyl alcohol poly. Strong lewis or mineral acids, strong oxidizing agents, strong mineral and organic bases especially primary and secondary aliphatic amines conditions to avoid. Foamit 3, foamit 5, foamit 10 and foamit 15 part b general use. Vinyl acetate from ethylene, acetic acid and oxygen.
Use dry chemical powder, water spray fog or carbon dioxide. Sds in compliance with provisions of information as set out in canadian standard part 4, schedule 1 and 2 of the. Vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. Chemical product and company identification product name. Eu 0605301771 38 do not lay the container on its side. There is no evidence that vinyl acetate causes cancer in humans.
Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. First aid measures ensure that medical personnel are aware of the materials involved, take precautions to protect themselves and prevent spread of contamination. When released into water, this material may biodegrade to a moderate extent. Material safety data sheet msds vinyl acetate monomer s. According to information 6,154,000 tonnesannum was produced globally in the year 2007. Page 2 of 2 may 1, 2001 material safety data sheet product name. Material safety data sheetmsds ethyl acetate synonyms. Lamination of glass for decorative or functional use. Do not eat, drink or smoke when using this product.
Vinyl acetate is slightly or moderately toxic to humans and animals. Lambda dna, ecor1 digest in 1x trisedta buffer, part number 85008536 while this material is not considered hazardous by the osha hazard communication standard 29 cfr 1910. Na handling and storage continued transport information continued. Vinyl acetate monomer safety data sheet international vinyl acetate company safety data sheet according to regulation ec no. This translates to an average molecular weight of between 850 and 40,000. India veritas house, 70 mint road, fort, mumbai 400 001. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in uae, europe, africa, usa.
When released into the soil, this material may evaporate to a moderate extent. Material safety data sheet celanese eva performance polymers. Released into the environment the vinyl acetate evaporates easily, being degraded rapidly by photochemical reactions, as well as biodegraded. Pva with a molecular weight of 3,000 da and a content of acetate groups 0. Fisher scientific 1 reagent lane fair lawn, nj 07410. Vinyl acetate monomer may irritate the skin, eyes, and respiratory tract.
We offer halal and kosher polyvinyl acetate made in an iso9001, iso22000 fssc22000 and cgmp certified facility. Bioeazetm bags ethyl vinyl acetate eva film united states safc biosciences, inc. View or download the ammonium acetate msds material safety data sheet or sds for 101116 from merck. Vinyl acetate is primarily used as a monomer in the production of polyvinyl acetate and polyvinyl alcohol. Products regulations cpr and the msds contains all the information required by the cpr hmis ratings for this product are. Ethylenevinyl acetate copolymer 24937788 99 vinyl acetate 108054. Material safety data sheet celanese eva performance. Fine dust clouds may form explosive mixtures with air. Keep polyvinyl acetate in a well closed container stored under cold to warm conditions, 2 to 40 c, 36 to 104f in a ventilated area. Report covers free delivery possible on eligible purchases.
Nonisothermal crystallization and melting of ethylenevinyl acetate copolymers with different vinyl acetate contents x. American polymer standards corporation safety data sheet. Polyvinyl acetate may be used as is or modified through. Vam is a key ingredient in emulsion polymers, resins, and intermediates used in paints, adhesives, coatings, textiles, wire and cable polyethylene compounds, laminated. Page 1 of 6 june 23, 2014 continued on next page section 1. Acute shortterm inhalation exposure of workers to vinyl acetate has resulted in eye irritation and upper respiratory tract irritation.
Toxicological profile for vinyl acetate agency for. A stock solution of vinyl acetate in methanol is prepared by pipetting 2 ml of vinyl acetate into a 25ml volumetric flask and diluting to volume with methanol. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Prolonged exposure can can defat the skin and cause dermatitis. Vam is a key ingredient in emulsion polymers, resins, and intermediates used in paints. Ac183250000, ac183250010, ac183250250, ac183255000 synonyms.
Preparation of divinyl esters by transvinylation between vinyl acetate and dicarboxylic acids. When handled properly, vam can be stored, transported and otherwise managed safely. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Composition information on ingredients common name terpineol synonyms terpineol normal formula c 10 h 18 o cas number 8000417 component cas number concentration terpineol 8000417 acetate is a substance produced through the combining of many units of monomeric vinyl acetate ch3coochch2. A water solution of pva was mixed with a pvac suspension 10% of polymer in both. Firefighting measures suitable extinguishing media.
No component of this product, present at levels greater than or equal to 0. Material safety data sheet poly vinyl acetate, average m. Vinyl acetate monomer vam is a high volume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. The number of units so combined is typically between 100 and 5,000. Use dry chemical powder, water spray fog or carbon dioxide unsuitable extinguishing media. Ethyl acetate safety data sheet jubilant life sciences limited ch. No data available specific target organ toxicity repeated exposure. Do not enter storage areas and confined spaces unless adequately ventilated. These polymers are the base for many industrial and consumer products as well as for other polymers. Synonyms of vinyl acetate are vinyl ester acetic acid, ethenyl ester, vinyl acetate monomer, vam, ethenyl acetate, 1acetoxyethylene. Polyvinyl acetate is a substance produced through the combining of many units of monomeric vinyl acetate ch3coochch2. Vinyl acetate is flammable in air percent by volume. Material safety data sheet ehylene vinyl acetate copolymer section 1 product and company identification manufacturer.
Vinyl acetate monomer safety data sheet international. The chemical formula for vinyl acetate isc h o, and its molecular weight is 86. Material safety data sheet polyvinyl acetate, average m. Nonisothermal crystallization and melting of ethylene. Sigmaaldrich material safety data sheet date printed. Vinyl acetate caused tumors in the noses of rats that breathed 600 ppm for 2 years. Ethylene vinyl acetate copolymer 24937788 99 vinyl acetate 108054 vinyl acetate monomer exposure. Synonyms acetidin, acetic acid ethyl ester, ethyl acetic ester. The substance identity section is calculated from substance identification information from all echa databases. When released into the soil, this material may leach into gro undwater. This sds was prepared in accordance with 29 cfr 1910.